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Rate equation

In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. For many reactions, the…

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Overview

Definition

Power laws

Complex laws

Opposed reactions

Consecutive reactions

Stoichiometric reaction networks

General dynamics of unimolecular conversion

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Rate equation

Nodes112
Edges111
Triples31
Avg. degree1.98
Density0.017857
Components1

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Rate equation

Top relations

related to Negative order · 5
Rate equation → For, In, O3, This, When
related to One first order and one second order reaction · 5
Rate equation → Concentration, For, H2O, The, This
related to Pseudo-first order · 4
Rate equation → For, If, One, The
see also · 4
Rate equation → Menten, Michaelis, Volterra, Zhabotinsky
related to Consecutive reactions · 3
Rate equation → If, The, With
is a · 1
Rate equation → power law
related to Power laws · 1
Rate equation → The
related to Two first order reactions · 1
Rate equation → The

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Important terminology

rate reaction displaystyle order concentration equation ce reactions reactant concentrations constant time example stoichiometric reactants one law orders elementary zero

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Rate equationis apower law0.90text
v 0instance ofthe initial rate is given by a power law0.80text
temperatureinstance ofIts value may depend on conditions0.80text
ionic strengthinstance ofIts value may depend on conditions0.80text
surface area of an adsorbentinstance ofIts value may depend on conditions0.80text
or light irradiationinstance ofIts value may depend on conditions0.80text
free radicalsinstance ofThe order of a chain reaction can be rationalized using the steady state approximation for the concentration of reactive intermediates0.80text
these can be formulated as a master equationinstance oflinear systems of differential equations0.80text
Rate equationrelated to Consecutive reactionsIf0.60section
Rate equationrelated to Consecutive reactionsWith0.60section
Rate equationrelated to Consecutive reactionsThe0.60section
Rate equationrelated to Negative orderFor0.60section

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