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Metallocene

A metallocene is a compound typically consisting of two cyclopentadienyl anions (C5H−5, abbreviated Cp) bound to a metal center (M). They have the general formula (C5R5)2M]+ (R = H, alkyl typically). Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their…

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Overview

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Definition

Synthesis

Structure

Spectroscopic properties

Derivatives

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Additional references

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Map overview Semantic statistics

Metallocene

Nodes89
Edges88
Triples111
Avg. degree1.98
Density0.022472
Components1

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Metallocene

Top relations

related to Additional references · 27
Metallocene → Chem, Cotton, Crabtree, Donald, Gary, Halterman, Inorganic Chemistry, ISBN, Metallocenes, NJ, Nomenclature, Organometallic Compounds, Pearson Education, Pure Appl, Robert, S2CID, Salzer, Tarr, The Organometallic Chemistry, Togni
related to history · 25
Metallocene → Arapahoe Chemicals, Boulder, C10H10Fe, C10H10Fe At, C5H5, Chemistry, Co, Colorado, Cp, Ernst Otto Fischer, FeCl3, Fischer, Geoffrey Wilkinson, Kealy, Metallocenes, Miller, Ni, Nobel Prize, Often, One
has application · 13
Metallocene → Cp2MX2, Early, Many, Mo, Natta, Nb, Petasis, Schwartz's, Tebbe's, The, Ti, Unlike, Ziegler
related to Definition · 13
Metallocene → According, Applied Chemistry, C5H5, Cp, Cp2Fe, For, II, In, International Union, IUPAC, Pure, The, Using
related to Structure · 8
Metallocene → C5R5, Crystals, For, In, M-C, MCp2, Single, X-ray
related to Metallocenium ions · 6
Metallocene → C5H5, Fe, II, III, Li, The
related to Mass spectrometry of metallocenes · 4
Metallocene → C10H10M, C5H5M, Mass, The
related to Metallocenophanes · 3
Metallocene → Ansa-metallocenes, Metallocenophanes, Some
related to Possible exception · 3
Metallocene → Although, IUPAC, Some
related to Vibrational (infrared and Raman) spectroscopy of metallocenes · 3
Metallocene → Infrared, Raman, Some

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Important terminology

metallocenes cyclopentadienyl derivatives ferrocene metal compounds sandwich two rings cp cyclopentadiene staggered complexes anions properties structure oxidation isbn et al

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Metalloceneis acompound typically consisting of two cyclopentadienyl anions0.90text
Metallocenehas applicationMany0.60section
Metallocenehas applicationUnlike0.60section
Metallocenehas applicationZiegler0.60section
Metallocenehas applicationNatta0.60section
Metallocenehas applicationEarly0.60section
Metallocenehas applicationTebbe's0.60section
Metallocenehas applicationPetasis0.60section
Metallocenehas applicationSchwartz's0.60section
Metallocenehas applicationThe0.60section
Metallocenehas applicationCp2MX20.60section
Metallocenehas applicationTi0.60section

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