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Eclipsed conformation

In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X–A–B–Y is 0°. Such a conformation can exist in any open chain, single chemical bond connecting two sp3-hybridised atoms, and it is normally a conformational energy maximum. This…

Applications, Structural applications & Organic chemistry

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Organic chemistry

Structural applications

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Eclipsed conformation

Nodes32
Edges31
Triples20
Avg. degree1.94
Density0.0625
Components1

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Eclipsed conformation

Top relations

has application · 9
Eclipsed conformation → Another, As, Experiments, II, It, Mo, Mo2Cl8, This, X-ray
related to Organic chemistry · 5
Eclipsed conformation → Conformations, Different, In, Newman, The
is a · 1
Eclipsed conformation → conformation in which two substituents X and Y on adjacent atoms A

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Important terminology

conformation bond eclipsed conformations two atoms another groups energy one methyl staggered butane energies rotation 60 angle ethane different due

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Eclipsed conformationis aconformation in which two substituents X and Y on adjacent atoms A0.90text
X-rayinstance ofThis sterically unfavorable geometry is given as evidence for a quadruple bond between the Mo centers.Experiments0.80text
electron diffraction analysesinstance ofThis sterically unfavorable geometry is given as evidence for a quadruple bond between the Mo centers.Experiments0.80text
nuclear magnetic resonanceinstance ofThis sterically unfavorable geometry is given as evidence for a quadruple bond between the Mo centers.Experiments0.80text
microwave spectroscopiesinstance ofThis sterically unfavorable geometry is given as evidence for a quadruple bond between the Mo centers.Experiments0.80text
and more have allowed researchers to determine which cycloalkane structures are the most stable based on the different possible conformationsinstance ofThis sterically unfavorable geometry is given as evidence for a quadruple bond between the Mo centers.Experiments0.80text
Eclipsed conformationhas applicationAs0.60section
Eclipsed conformationhas applicationX-ray0.60section
Eclipsed conformationhas applicationII0.60section
Eclipsed conformationhas applicationMo2Cl80.60section
Eclipsed conformationhas applicationThis0.60section
Eclipsed conformationhas applicationMo0.60section

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