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Macrocycles are often described as molecules and ions containing a ring of twelve or more atoms. Classical examples include the crown ethers, calixarenes, porphyrins, and cyclodextrins. Macrocycles describe a large, mature area of chemistry.
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macrocyclic conformation ring rings state stereocontrol macrocycles conformational energy ground conformations reactions reaction peripheral attack interactions methyl molecules synthesis preferences
| Subject | Predicate | Object | Confidence | Src |
|---|---|---|---|---|
| in the synthesis of miyakolide.Reaction classes used in synthesis of natural products under the macrocyclic stereocontrol model for obtaining a desired stereochemistry include | instance of | providing stereocontrol | 0.80 | text |
| Macrocycle | has application | One | 0.60 | section |
| Macrocycle | has application | Many | 0.60 | section |
| Macrocycle | has application | These | 0.60 | section |
| Macrocycle | has application | Macrocycles | 0.60 | section |
| Macrocycle | has application | The | 0.60 | section |
| Macrocycle | related to Conformational preferences | Macrocycles | 0.60 | section |
| Macrocycle | related to Conformational preferences | Medium | 0.60 | section |
| Macrocycle | related to Conformational preferences | Conformational | 0.60 | section |
| Macrocycle | related to Further reading | Chambron | 0.60 | section |
| Macrocycle | related to Further reading | J-C | 0.60 | section |
| Macrocycle | related to Further reading | Dietrich-Buchecker | 0.60 | section |
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