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Ligand cone angle

In coordination chemistry, the ligand cone angle (θ) is a measure of the steric bulk of a ligand in a transition metal coordination complex. It is defined as the solid angle formed with the metal at the vertex of a cone and the outermost edge of the van der Waals spheres of the ligand atoms at the perimeter of the base of the cone. Tertiary phosphine…

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Ligand cone angle

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Edges18
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Avg. degree1.89
Density0.105263
Components1

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angle cone ligand tolman metal ligands method phosphine center steric solid perimeter concept half bond coordination parameter research nickel complexes

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