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In coordination chemistry, the first coordination sphere refers to the array of molecules and ions (the ligands) directly attached to the central metal atom. The second coordination sphere consists of molecules and ions that attached in various ways to the first coordination sphere.
Second coordination sphere, First coordination sphere & Overview
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coordination sphere second first molecules metal ions ligands complexes ligand attached chemistry reactions spheres often effects refers directly central atom
| Subject | Predicate | Object | Confidence | Src |
|---|---|---|---|---|
| Coordination sphere | is a | first step in ligand substitution reactions | 0.90 | text |
| contrast agents used in MRI.The energetics of inner sphere electron transfer reactions are discussed in terms of second coordination sphere | instance of | These effects are relevant to practical applications | 0.80 | text |
| cyclodextrins act often as the second coordination sphere for metal complexes | instance of | Polyammonium cations bind to the nitrogen centres of cyanometallates.Role in supramolecular chemistryMacrocyclic molecules | 0.80 | text |
| cyclodextrins act often as the second coordination sphere for metal complexes | instance of | Role in supramolecular chemistryMacrocyclic molecules | 0.80 | text |
| Coordination sphere | related to First coordination sphere | The | 0.60 | section |
| Coordination sphere | related to First coordination sphere | For | 0.60 | section |
| Coordination sphere | related to First coordination sphere | In | 0.60 | section |
| Coordination sphere | related to First coordination sphere | III | 0.60 | section |
| Coordination sphere | related to First coordination sphere | Co | 0.60 | section |
| Coordination sphere | related to First coordination sphere | NH3 | 0.60 | section |
| Coordination sphere | related to First coordination sphere | Cl3 | 0.60 | section |
| Coordination sphere | related to First coordination sphere | MN6 | 0.60 | section |
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