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Bite angle

In coordination chemistry, the bite angle is the angle on a central atom between two bonds to a bidentate ligand. This ligand–metal–ligand geometric parameter is used to classify chelating ligands, including those in organometallic complexes. It is most often discussed in terms of catalysis, as changes in bite angle can affect not just the activity and…

Diphosphines, A case study: hydroformylation & Diamines

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Overview

Diamines

Diphosphines

The natural bite angle

A case study: hydroformylation

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Map overview Semantic statistics

Bite angle

Nodes29
Edges28
Triples14
Avg. degree1.93
Density0.068966
Components1

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Bite angle

Top relations

related to Diamines · 6
Bite angle → Diamines, Examples, Longer, Six-membered, The, They
related to The natural bite angle · 4
Bite angle → Both, Figure, The, This
is a · 1
Bite angle → angle on a central atom between two bonds to a bidentate ligand

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Important terminology

bite angle ligands diphosphine ligand angles complexes steric diphosphines hydroformylation also effect equatorial two metal wide chelating phosphine backbone figure

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Bite angleis aangle on a central atom between two bonds to a bidentate ligand0.90text
dppeinstance ofDiphosphine ligands0.80text
which has a bite angle of about 90instance ofDiphosphine ligands0.80text
BISBIinstance ofthe use of diphosphine ligands with wide bite angles0.80text
Bite anglerelated to DiaminesDiamines0.60section
Bite anglerelated to DiaminesThey0.60section
Bite anglerelated to DiaminesExamples0.60section
Bite anglerelated to DiaminesSix-membered0.60section
Bite anglerelated to DiaminesThe0.60section
Bite anglerelated to DiaminesLonger0.60section
Bite anglerelated to The natural bite angleThe0.60section
Bite anglerelated to The natural bite angleFigure0.60section

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    Min side: 3
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