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Diradicaloid

Biradicaloids or diradicaloids are molecules with two radical electrons that have significant interaction with each other. The two unpaired electrons are coupled and can either form a singlet ground state (antiferromagnetic coupling) or a triplet ground state (ferromagnetic coupling) (Figure 1).

Theoretical description, Overview & Reactivity

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Overview

Theoretical description

Synthesis

Reactivity

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Map overview Semantic statistics

Diradicaloid

Nodes81
Edges80
Triples33
Avg. degree1.98
Density0.024691
Components1

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Diradicaloid

Top relations

has application · 8
Diradicaloid → After, Diradicaloids, Figure, For, Hetero-cyclopentane-1, This, Thus, Upon
related to Closed-shell reactivity · 8
Diradicaloid → Figure, For, From, H2, HOMO, LUMO, NTer, Only
related to Other main group diradicaloids · 8
Diradicaloid → B2C2, Braunschweig, C4Ge2, Calculations, EPR, Gilliard, HOMO-LUMO, In
related to Open-shell reactivity · 7
Diradicaloid → Figure, For, In, Kendall Houk, Neil Garg, NTer, The
related to Reactivity · 2
Diradicaloid → Closed-shell, Diradicaloids

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Important terminology

diradical character species displaystyle diradicaloids radical figure state singlet ring wavefunction two planar electrons phosphorus also coworkers synthesized bond carbon

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Diradicaloidhas applicationHetero-cyclopentane-10.60section
Diradicaloidhas applicationDiradicaloids0.60section
Diradicaloidhas applicationFor0.60section
Diradicaloidhas applicationFigure0.60section
Diradicaloidhas applicationUpon0.60section
Diradicaloidhas applicationAfter0.60section
Diradicaloidhas applicationThus0.60section
Diradicaloidhas applicationThis0.60section
Diradicaloidrelated to Closed-shell reactivityFor0.60section
Diradicaloidrelated to Closed-shell reactivityNTer0.60section
Diradicaloidrelated to Closed-shell reactivityH20.60section
Diradicaloidrelated to Closed-shell reactivityFigure0.60section

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