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Aryne

In organic chemistry, arynes and benzynes are a class of highly reactive chemical species derived from an aromatic ring by removal of two substituents. Arynes are examples of didehydroarenes (1,2-didehydroarenes in this case), although 1,3- and 1,4-didehydroarenes are also known. Arynes are examples of alkynes under high strain.

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Overview

Bonding in arynes

Generation of arynes

Reactions of arynes

Other dehydrobenzenes

History

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Aryne

Nodes55
Edges54
Triples41
Avg. degree1.96
Density0.036364
Components1

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Aryne

Top relations

related to Nucleophilic additions to arynes · 8
Aryne → Aryl, E1cb, E2, Generation, Isotope, The, Thus, Upon
related to history · 7
Aryne → Based, In, Kahlert, Stoermer, The, This, Wittig
related to Bonding in arynes · 5
Aryne → Arynes, Geometric, Nevertheless, Radziszewski, The
related to Examples of benzynes in total synthesis · 4
Aryne → Indeed, Nucleophilic, The, Their
related to External links · 4
Aryne → Arynes, Media, Wikimedia Commons, Wiktionary-logo-en-v2
related to Generation of arynes · 4
Aryne → Due, Early, Such, Typical
related to Other dehydrobenzenes · 4
Aryne → Extremely, If, The, Their
related to Reactions of arynes · 2
Aryne → Even, Their
see also · 2
Aryne → Examples, TricyclobutabenzeneIn-methylcyclophaneTransition
related to Bond-insertion reactions of arynes · 1
Aryne → The

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Important terminology

benzyne arynes synthesis reactions reaction examples 4-didehydrobenzene nucleophilic intermediate product two benzynes generated natural additions total substituents triple bond form

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Arynerelated to Bond-insertion reactions of arynesThe0.60section
Arynerelated to Bonding in arynesThe0.60section
Arynerelated to Bonding in arynesArynes0.60section
Arynerelated to Bonding in arynesGeometric0.60section
Arynerelated to Bonding in arynesRadziszewski0.60section
Arynerelated to Bonding in arynesNevertheless0.60section
Arynerelated to Examples of benzynes in total synthesisNucleophilic0.60section
Arynerelated to Examples of benzynes in total synthesisIndeed0.60section
Arynerelated to Examples of benzynes in total synthesisThe0.60section
Arynerelated to Examples of benzynes in total synthesisTheir0.60section
Arynerelated to External linksWiktionary-logo-en-v20.60section
Arynerelated to External linksMedia0.60section

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