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Van der Waals strain

Van der Waals strain is strain resulting from Van der Waals repulsion when two substituents in a molecule approach each other with a distance less than the sum of their Van der Waals radii. Van der Waals strain is also called Van der Waals repulsion and is related to steric hindrance. One of the most common forms of this strain is eclipsing hydrogen, in…

In rotational and pseudorotational mechanisms & Overview

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In rotational and pseudorotational mechanisms

Vibrational modeBerry mechanismBartell mechanismPotential energyPF5
9 related topics

Overview

StrainVan der WaalsSubstituentsMoleculeVan der Waals radii
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In rotational and pseudorotational mechanisms

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Van der Waals strain

Nodes20
Edges19
Triples8
Avg. degree1.9
Density0.1
Components1

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Van der Waals strain

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related to In rotational and pseudorotational mechanisms · 8
Van der Waals strain → Bartell, Berry, Despite, In, PCl5, PF5, Van, Waals

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Important terminology

strain van der waals molecule repulsion also substituents potential energy rotational pseudorotational alkanes mechanism identical geometry resulting two approach distance

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SubjectPredicateObjectConfidenceSrc
Van der Waals strainrelated to In rotational and pseudorotational mechanismsIn0.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsBerry0.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsBartell0.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsVan0.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsWaals0.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsPF50.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsPCl50.60section
Van der Waals strainrelated to In rotational and pseudorotational mechanismsDespite0.60section

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