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Trans effect

In inorganic chemistry, the trans effect is the increased lability of ligands that are trans to certain other ligands, which can thus be regarded as trans-directing ligands. It is attributed to electronic effects and it is most notable in square planar complexes, although it can also be observed for octahedral complexes. The analogous cis effect is most…

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Products, Kinetic trans effect & Structural trans effect

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Kinetic trans effect

26 related topics

Structural trans effect

1 related topics

Overview

8 related topics

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Overview

Kinetic trans effect

Structural trans effect

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Trans effect

Nodes39
Edges38
Triples35
Avg. degree1.95
Density0.051282
Components1

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Trans effect

Top relations

related to Further reading · 15
Trans effect → Basolo, Chem, Chemical Reviews, Chemical Society Reviews, Complex Inorganic Compounds, CS9730200163, Hartley, Inorg, LEO, Pearson, Prog, Quagliano, Schubert, The, The Trans Effect
related to Kinetic trans effect · 11
Trans effect → As, Cl, Dhara, Magnus's, NH3, One, PtCl2, PtCl3NH3, PtCl42, PtI4, The
related to Structural trans effect · 3
Trans effect → Stretching, The, X-ray
is a · 2
Trans effect → increased lability of ligands that are trans to certain other ligands, synthesis of cisplatin and its trans isomer

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Important terminology

trans effect ligands complexes also observed kinetic metal influence structural ligand cis attributed notable octahedral one equatorial inorganic square addition

Entity relationships Subject–Predicate–Object triples

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SubjectPredicateObjectConfidenceSrc
Trans effectis aincreased lability of ligands that are trans to certain other ligands0.90text
Trans effectis asynthesis of cisplatin and its trans isomer0.90text
structural trans effect or thermodynamic trans effect.The discovery of the trans effect is attributed to Ilya Ilich Chernyaevinstance ofwhile others use more specific terms0.80text
who recognized itinstance ofwhile others use more specific terms0.80text
gave it a name in 1926instance ofwhile others use more specific terms0.80text
hydrideinstance ofStretching by as much as 0.2 Å occurs with strong trans-influencing ligands0.80text
Trans effectrelated to Further readingQuagliano0.60section
Trans effectrelated to Further readingSchubert0.60section
Trans effectrelated to Further readingLEO0.60section
Trans effectrelated to Further readingThe Trans Effect0.60section
Trans effectrelated to Further readingComplex Inorganic Compounds0.60section
Trans effectrelated to Further readingChemical Reviews0.60section

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