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Cis effect

In inorganic chemistry, the cis effect is defined as the labilization (or destabilization) of CO ligands that are cis to other ligands. CO is a well-known strong pi-accepting ligand in organometallic chemistry that will labilize in the cis position when adjacent to ligands due to steric and electronic effects. The system most often studied for the cis…

Ligands effects on CO cis-labilization, Electron counting in metal carbonyl complexes & Overview

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Ligands effects on CO cis-labilization

H−PPh3I−CH3COBr−
17 related topics

Electron counting in metal carbonyl complexes

Group 6Group 7Oxidation state18 electronValence orbitals
12 related topics

Overview

Inorganic chemistryCOLigandsCisPi
14 related topics

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Electron counting in metal carbonyl complexes

Ligands effects on CO cis-labilization

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Cis effect

Nodes47
Edges46
Triples1
Avg. degree1.96
Density0.042553
Components1

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Cis effect

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is a · 1
Cis effect → octahedral complex M

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Important terminology

co ligands cis ligand complexes effect effects trans metal sigma transition complex strong electron dissociation pi-accepting 5x donors chemistry octahedral

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SubjectPredicateObjectConfidenceSrc
Cis effectis aoctahedral complex M0.90text

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