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Reductive elimination

Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive elimination…

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Overview

General information

Mechanisms

Factors that affect reductive elimination

Applications

Advanced semantic analysis

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Map overview Semantic statistics

Reductive elimination

Nodes41
Edges40
Triples48
Avg. degree1.95
Density0.04878
Components1

How this topic connects Entity context

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Reductive elimination

Top relations

related to General information · 13
Reductive elimination → Additionally, Au, For, II, III, Ir, IV, Ni, Pd, Pt, Reductive, Rh, This
related to Octahedral complexes · 6
Reductive elimination → After, In, T-shaped, The, This, Y-type
has application · 5
Reductive elimination → Heck, In, Monsanto, Reductive, Wacker
related to Square planar complexes · 5
Reductive elimination → For, If, In, Reductive, Similar
related to Mechanisms · 4
Reductive elimination → As, In, SN2, The
related to Coordination number · 3
Reductive elimination → For, Reductive, When
related to Metal identity and electron density · 3
Reductive elimination → Additionally, First-row, This
is a · 2
Reductive elimination → elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands, product forming step and regenerates the catalyst
related to Factors that affect reductive elimination · 2
Reductive elimination → Additionally, Reductive
related to Sterics · 2
Reductive elimination → Additionally, Reductive

Important terminology Word statistics

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Important terminology

elimination reductive metal complexes oxidation complex state center addition ligand reactions oxidative ligands mechanisms octahedral must mechanism two step reverse

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Reductive eliminationis aelementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands0.90text
Reductive eliminationis aproduct forming step and regenerates the catalyst0.90text
Reductive eliminationhas applicationReductive0.60section
Reductive eliminationhas applicationMonsanto0.60section
Reductive eliminationhas applicationIn0.60section
Reductive eliminationhas applicationHeck0.60section
Reductive eliminationhas applicationWacker0.60section
Reductive eliminationrelated to Coordination numberReductive0.60section
Reductive eliminationrelated to Coordination numberFor0.60section
Reductive eliminationrelated to Coordination numberWhen0.60section
Reductive eliminationrelated to Factors that affect reductive eliminationReductive0.60section
Reductive eliminationrelated to Factors that affect reductive eliminationAdditionally0.60section

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