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Transition metal pincer complex

In chemistry, a transition metal pincer complex is a type of coordination complex with a pincer ligand. Pincer ligands are chelating agents that binds tightly to three adjacent coplanar sites in a meridional configuration. The inflexibility of the pincer-metal interaction confers high thermal stability to the resulting complexes. This stability is in…

History, Types of pincer ligands & Scope of pincer ligands

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Types of pincer ligands

PlanarPhosphineTridentateTransition metalCatalysis
10 related topics

Scope of pincer ligands

PyridinesPOCOPTerpyridineC-H bond activationPincer complexes
8 related topics

History

Tert-butyl
1 related topics

Role in catalysis

Suzuki-MiyauraMonodentateDehydrogenation
3 related topics

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Scope of pincer ligands

Types of pincer ligands

Synthesis

Role in catalysis

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Transition metal pincer complex

Nodes40
Edges39
Triples3
Avg. degree1.95
Density0.05
Components1

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Transition metal pincer complex

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is a · 1
Transition metal pincer complex → type of coordination complex with a pincer ligand

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Important terminology

pincer ligands complexes metal ligand donor coordination sites dehydrogenation often also reactions pcp phosphine found citation needed complex high bond

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SubjectPredicateObjectConfidenceSrc
Transition metal pincer complexis atype of coordination complex with a pincer ligand0.90text
alkene metathesisinstance ofoxidation state which allows stronger Ir-C and Ir-H bonds.The homogeneously catalyzed process can be coupled to other reactions0.80text
PtClinstance ofgiving species0.80text

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