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Negative hyperconjugation in silicon

Negative hyperconjugation is a theorized phenomenon in organosilicon compounds, in which hyperconjugation stabilizes or destabilizes certain accumulations of positive charge. The phenomenon explains corresponding peculiarities in the stereochemistry and rate of hydrolysis.

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Negative hyperconjugation in silicon

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silicon hydrolysis effect carbon si atom orbital group certain effects hyperconjugation reactivity rate generally stabilize however compounds corresponding negative electronegativity

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