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MoOPH

MoOPH, also known as oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide), is a reagent used in organic synthesis. It contains a molybdenum(VI) center with multiple oxygen ligands, coordinated with pyridine and HMPA ligands, although the HMPA can be replaced by DMPU. It is an electrophilic source of oxygen that reacts with enolates and related…

Standards, Reactivity & Overview

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Overview

Synthesis

Reactivity

Advanced semantic analysis

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Map overview Semantic statistics

MoOPH

Nodes28
Edges27
Triples13
Avg. degree1.93
Density0.071429
Components1

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MoOPH

Top relations

related to Synthesis · 10
MoOPH → H2O, H2O2, HMPA, MoO, MoO3, MoO5, Pyridine, Pyridine MoO, Torr, Torr MoO
related to Reactivity · 3
MoOPH → Due, In, MoOPH's

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Important terminology

pyridine oxygen hmpa reagent alpha-hydroxylation used include directly enolate structures synthesis oxodiperoxymolybdenum hexamethylphosphoric triamide vedejs molybdenum references addition also ligands

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
MoOPHrelated to ReactivityDue0.60section
MoOPHrelated to ReactivityMoOPH's0.60section
MoOPHrelated to ReactivityIn0.60section
MoOPHrelated to SynthesisHMPA0.60section
MoOPHrelated to SynthesisMoO0.60section
MoOPHrelated to SynthesisTorr MoO0.60section
MoOPHrelated to SynthesisPyridine MoO0.60section
MoOPHrelated to SynthesisMoO30.60section
MoOPHrelated to SynthesisH2O20.60section
MoOPHrelated to SynthesisMoO50.60section
MoOPHrelated to SynthesisH2O0.60section
MoOPHrelated to SynthesisTorr0.60section

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