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BTBP

The bis-triazinyl bipyridines (BTBPs) are a class of chemical compounds which are tetradentate ligands similar in shape to quaterpyridine. The BTBPs are made by the reaction of hydrazine and a 1,2-diketone (such as hexane-3,4-dione) with 6,6'-dicyano-2,2'-bipyridine. The dicyanobipy can be made by reacting 2,2'-bipy with hydrogen peroxide in acetic acid…

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BTBP

Nodes50
Edges49
Triples2
Avg. degree1.96
Density0.04
Components1

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Important terminology

btbps form extraction lanthanides nitrogens nickel uranium made acid mixture bind complexes complex nitrogen crystallography axial americium bis-triazinyl reaction 2'-bipyridine-n

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
nickel the BTBPs are may bind with three nitrogens in some complexesinstance ofwith a smaller metal0.80text
americium from nitric acid solutions containing large amounts of lanthanidesinstance ofThe BTBPs are also able to bind to cyclopentadienyl complexes of uranium.In recent years the BTBPs have been investigated as reagents for the selective extraction of post-pluton…0.80text

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