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BINAP

BINAP (2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) is an organophosphorus compound. This chiral diphosphine ligand is widely used in asymmetric synthesis. It consists of a pair of 2-diphenylphosphinonaphthyl groups linked at the 1 and 1′ positions. This C2-symmetric framework lacks a stereogenic atom, but has axial chirality due to restricted rotation…

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Use as ligand in asymmetric catalysis

Organic synthesisEnantioselectiveComplexesRutheniumRhodium
14 related topics

Overview

Organophosphorus compoundChiralDiphosphineLigandAsymmetric synthesis
14 related topics

Preparation

BINOLTriflateEnantiomers
3 related topics

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Overview

Use as ligand in asymmetric catalysis

Preparation

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BINAP

Nodes35
Edges34
Triples63
Avg. degree1.94
Density0.057143
Components1

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BINAP

Top relations

related to Further reading · 56
BINAP → Aderibigbe, Andrew, Asymmetric Catalysis, Asymmetric Hydrogenation, Ayad, Berthod, Bidentate Phosphines, Binaphthyls, Butt, Chemical Reviews, Clevenger, DIFLUORPHOS, Electron-Deficient Diphosphines, Enantioselective Catalysis, Gary, Genet, Gérard, Janis, Jean-Pierre, Justis
related to Use as ligand in asymmetric catalysis · 4
BINAP → As, BINAP-AgF, Ryōji Noyori, Silver
related to Preparation · 3
BINAP → BINOL, Both, One

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Important terminology

chemical doi pmid asymmetric reviews 10 1021 angle ligand catalysis naphthyl used synthesis groups due rotation enantioselective complexes rhodium references

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
BINAPrelated to Further readingLock-green0.60section
BINAPrelated to Further readingLock-gray-alt-20.60section
BINAPrelated to Further readingLock-red-alt-20.60section
BINAPrelated to Further readingWikisource-logo0.60section
BINAPrelated to Further readingBerthod0.60section
BINAPrelated to Further readingMikaël0.60section
BINAPrelated to Further readingMignani0.60section
BINAPrelated to Further readingGérard0.60section
BINAPrelated to Further readingWoodward0.60section
BINAPrelated to Further readingGary0.60section
BINAPrelated to Further readingLemaire0.60section
BINAPrelated to Further readingMarc0.60section

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