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Alkoxide

In chemistry, an alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom. They are written as RO−, where R is the organyl substituent. Alkoxides are strong bases[citation needed] and, when R is not bulky, good nucleophiles and good ligands. Alkoxides, although generally not stable…

Overview, Properties & Illustrative alkoxides

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Overview

Structure

Preparation

Properties

Illustrative alkoxides

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Alkoxide

Nodes48
Edges47
Triples41
Avg. degree1.96
Density0.041667
Components1

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Alkoxide

Top relations

related to From reducing metals · 8
Alkoxide → Alkoxides, Another, Generally, Highly, NaH, Other, The, Thus
related to Further reading · 8
Alkoxide → Bibcode, Metal, Nataliya, RC2004v073n11ABEH000855, Russian Chemical Reviews, S2CID, Synthesis, Turova
related to Structure · 7
Alkoxide → Alkali, Et, In, M2O, M3O, Me, The
related to Hydrolysis and transesterification · 4
Alkoxide → Aliphatic, In, Sodium, With
related to Thermal stability · 4
Alkoxide → Decomposition, Depending, Many, This
related to Reactions with alkyl halides · 3
Alkoxide → SN2, The, Williamson
related to Formation of oxo-alkoxides · 2
Alkoxide → Many, Oxo-ligands
is a · 1
Alkoxide → conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom

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Important terminology

alkoxides metal alcohol needed sodium used citation methoxide alkyl also group reaction metals oxygen enolates phenoxides transesterification potassium alkali solution

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Alkoxideis aconjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom0.90text
waterinstance ofalthough generally not stable in protic solvents0.80text
occur widely as intermediates in various reactionsinstance ofalthough generally not stable in protic solvents0.80text
including the Williamson ether synthesisinstance ofalthough generally not stable in protic solvents0.80text
NaHinstance ofAnother similar reaction occurs when an alcohol is reacted with a metal hydride0.80text
Alkoxiderelated to Formation of oxo-alkoxidesMany0.60section
Alkoxiderelated to Formation of oxo-alkoxidesOxo-ligands0.60section
Alkoxiderelated to From reducing metalsAlkoxides0.60section
Alkoxiderelated to From reducing metalsHighly0.60section
Alkoxiderelated to From reducing metalsThe0.60section
Alkoxiderelated to From reducing metalsOther0.60section
Alkoxiderelated to From reducing metalsGenerally0.60section

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