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Yamaguchi esterification

The Yamaguchi esterification is the chemical reaction of an aliphatic carboxylic acid and 2,4,6-trichlorobenzoyl chloride (TCBC, Yamaguchi reagent) to form a mixed anhydride which, upon reaction with an alcohol in the presence of stoichiometric amount of DMAP, produces the desired ester. It was first reported by Masaru Yamaguchi et al. in 1979.

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Reaction mechanism

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Yamaguchi esterification

Nodes14
Edges13
Triples11
Avg. degree1.86
Density0.142857
Components1

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Yamaguchi esterification

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related to External links · 10
Yamaguchi esterification → Article, Dhimitruka, Improved Esterification Method, Lett, Lux-S Enzyme Inhibitor Using, Org, SantaLucia, Synthesis, Yamaguchi, Yamaguchi Esterification Mechanism
is a · 1
Yamaguchi esterification → chemical reaction of an aliphatic carboxylic acid and 2

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Important terminology

reaction yamaguchi aliphatic anhydride alcohol dmap esterification ester reagent form mixed synthesis highly mechanism electrophilic attacked org chemical carboxylic acid

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Yamaguchi esterificationis achemical reaction of an aliphatic carboxylic acid and 20.90text
Yamaguchi esterificationrelated to External linksYamaguchi0.60section
Yamaguchi esterificationrelated to External linksYamaguchi Esterification Mechanism0.60section
Yamaguchi esterificationrelated to External linksSynthesis0.60section
Yamaguchi esterificationrelated to External linksLux-S Enzyme Inhibitor Using0.60section
Yamaguchi esterificationrelated to External linksImproved Esterification Method0.60section
Yamaguchi esterificationrelated to External linksDhimitruka0.60section
Yamaguchi esterificationrelated to External linksSantaLucia0.60section
Yamaguchi esterificationrelated to External linksOrg0.60section
Yamaguchi esterificationrelated to External linksLett0.60section
Yamaguchi esterificationrelated to External linksArticle0.60section

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