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Thiyl radical

In chemistry, a thiyl radical has the formula RS, sometimes written RS• to emphasize that they are free radicals. R is typically an alkyl or aryl substituent. Because S–H bonds are about 20% weaker than C–H bonds, thiyl radicals are relatively easily generated from thiols (RSH). Thiyl radicals are regularly invoked as intermediates in some biochemical…

Thiyl radical in biology, Structure & Formation

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Thiyl radical in biology

CysteineRibonucleotide reductaseEnzymeDeoxyribonucleotidesRibonucleotides
15 related topics

Structure

DisulfidesThiol-ene reactionAdhesives
3 related topics

Formation

AIBNRN=NR
2 related topics

Overview

ChemistryFree radicalsThiols
3 related topics

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Formation

Structure

Thiyl radical in biology

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Thiyl radical

Nodes28
Edges27
Triples17
Avg. degree1.93
Density0.071429
Components1

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Thiyl radical

Top relations

related to Elimination of thiyl radicals · 5
Thiyl radical → In, Isoprenoid, Nonetheless, Phenolic, Thus
related to Formation · 5
Thiyl radical → AIBN, OH, R-CHOO, The, Thiyl
related to Thiyl radical in biology · 3
Thiyl radical → It, RNR, Thiyl
related to Reactions · 2
Thiyl radical → The, Thiyl
related to Structure · 2
Thiyl radical → Claims, Thiyl

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Important terminology

radicals thiyl radical thiols 1s formation reactions high 109 substrates generated intermediates antioxidants α-tocopherol chemistry rapidly action peroxyl 103 reaction

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Thiyl radicalrelated to Elimination of thiyl radicalsPhenolic0.60section
Thiyl radicalrelated to Elimination of thiyl radicalsNonetheless0.60section
Thiyl radicalrelated to Elimination of thiyl radicalsIsoprenoid0.60section
Thiyl radicalrelated to Elimination of thiyl radicalsIn0.60section
Thiyl radicalrelated to Elimination of thiyl radicalsThus0.60section
Thiyl radicalrelated to FormationThiyl0.60section
Thiyl radicalrelated to FormationThe0.60section
Thiyl radicalrelated to FormationAIBN0.60section
Thiyl radicalrelated to FormationOH0.60section
Thiyl radicalrelated to FormationR-CHOO0.60section
Thiyl radicalrelated to ReactionsThe0.60section
Thiyl radicalrelated to ReactionsThiyl0.60section

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