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McMurry reaction

The McMurry reaction is an organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such as titanium(III) chloride and a reducing agent. The reaction is named after its co-discoverer, John E. McMurry. The McMurry reaction originally involved the use of a mixture TiCl3 and LiAlH4, which…

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Reaction mechanism

Background and scope

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McMurry reaction

Nodes39
Edges38
Triples21
Avg. degree1.95
Density0.051282
Components1

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McMurry reaction

Top relations

related to background · 16
McMurry reaction → Cu, Fleming, In, Japan, McMurry, Mukaiyama, Nicolaou's, Optimized, Other, Poland, Taxol, The, TiCl3, Tyrlik, USA, Zn
related to External links · 3
McMurry reaction → McMurry, Sussex, University
is a · 1
McMurry reaction → organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such as titanium

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Important terminology

reaction mcmurry titanium coupling species ticl3 zinc reducing groups using mixture related alkene organic named magnesium complex low-valent two coupled

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
McMurry reactionis aorganic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such as titanium0.90text
titaniuminstance ofThe McMurry reaction is an organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound0.80text
McMurry reactionrelated to backgroundThe0.60section
McMurry reactionrelated to backgroundMukaiyama0.60section
McMurry reactionrelated to backgroundJapan0.60section
McMurry reactionrelated to backgroundTyrlik0.60section
McMurry reactionrelated to backgroundPoland0.60section
McMurry reactionrelated to backgroundMcMurry0.60section
McMurry reactionrelated to backgroundUSA0.60section
McMurry reactionrelated to backgroundFleming0.60section
McMurry reactionrelated to backgroundOther0.60section
McMurry reactionrelated to backgroundIn0.60section

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