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Phosphaethynolate

The phosphaethynolate anion, also referred to as PCO, is the phosphorus-containing analogue of the cyanate anion with the chemical formula .mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output…

Products, Reactivity of the anion & Synthesis

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Overview

Synthesis

Ambidentate nature of the anion

Reactivity of the anion

Other analogues

Advanced semantic analysis

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Map overview Semantic statistics

Phosphaethynolate

Nodes60
Edges59
Triples67
Avg. degree1.97
Density0.033333
Components1

How this topic connects Entity context

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Phosphaethynolate

Top relations

related to Phosphorus transfer agents · 12
Phosphaethynolate → B3LYP/6-31, Brønsted, CO, Computational, Examples, Goicoechea, Grutzmacher, HPCO, In, N-heterocylic, PCO, The
related to Synthesis · 12
Phosphaethynolate → Becker, Becker's, C-O, Li, Like, P-C, PCO, Similar, Ten, The, They, Westerhausen
related to Ambidentate nature of the anion · 9
Phosphaethynolate → Computational, It, Natural Bond Orbital, Natural Resonance Theory, NBO, NRT, PCO, The, This
related to Attack by phosphorus · 9
Phosphaethynolate → Examples, Goicoechea, Grutzmacher, It, On, PCO, Re, The, This
related to Cycloaddition Reagents · 9
Phosphaethynolate → After, Cycloaddition, Goicoechea, Grutzmacher, NaPCO, One, PCO, They, This
related to Varying X · 7
Phosphaethynolate → As, Becker, PCO, PCS, The, This, Unlike PCO
related to Other analogues · 3
Phosphaethynolate → E-C-X, The, When
related to Reactivity of the anion · 2
Phosphaethynolate → Extensive, It

Important terminology Word statistics

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Important terminology

anion pco phosphorus oxygen atom salt bond coordination nature analogue et al work thus goicoechea involving also ambidentate character synthetic

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Natural Bond Orbitalinstance ofThis ambidentate character of the anion means that it is able to bind via both the phosphorus and oxygen atoms depending on the nature of the centre being coordinated.Computatio…0.80text
carbodiimidesinstance ofThey employed the same method to test other unsaturated substrates0.80text
found that the likelihood of cyclisation heavily relies on the nature of the substituents on the unsaturated substrate.Cycloaddition reactions involving the phosphaethynolate anion have also been shown by Grutzmacherinstance ofThey employed the same method to test other unsaturated substrates0.80text
co-workers to be a viable synthetic route to other heterocyclesinstance ofThey employed the same method to test other unsaturated substrates0.80text
Phosphaethynolaterelated to Ambidentate nature of the anionThe0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionIt0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionThis0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionComputational0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionNatural Bond Orbital0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionNBO0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionNatural Resonance Theory0.60section
Phosphaethynolaterelated to Ambidentate nature of the anionNRT0.60section

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