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Non-linear effects

In enantioselective synthesis, a non-linear effect refers to a process in which the enantiopurity of the catalyst (or the chiral auxiliary) does not correlate linearly with the enantiopurity of the product produced. This deviation from linearity is described as the non-linear effect, NLE. The linearity can be expressed mathematically, as shown in…

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Overview

Enantioselective synthesisEnantiopurityChiral auxiliaryMathematicallyEnantiomeric excess
19 related topics

Modeling non-linear effects

Henri B. KaganMetalLigandsGoodness of fitMechanistic
5 related topics

Prebiotic Catalysis and the Non-linear Effect

ChemistryAutocatalyticHomochiralitySoai reaction
4 related topics

Types of non-linear effects

EpoxidationGeraniolOxidations
3 related topics

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Overview

Types of non-linear effects

Modeling non-linear effects

Early Examples of the Non-Linear Effect

Prebiotic Catalysis and the Non-linear Effect

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Non-linear effects

Nodes38
Edges37
Triples7
Avg. degree1.95
Density0.052632
Components1

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Non-linear effects

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related to Hyperpositive and enantiodivergent non-linear effect · 7
Non-linear effects → Bellemin-Laponnaz, Beyond, Henri Kagan, Kagan's, ML3, The, This

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reaction model complexes effect non-linear heterochiral ml2 asymmetric rate catalytic catalyst product described case equation homochiral complex kagan -nle effects

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SubjectPredicateObjectConfidenceSrc
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectBeyond0.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectThis0.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectHenri Kagan0.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectML30.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectThe0.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectBellemin-Laponnaz0.60section
Non-linear effectsrelated to Hyperpositive and enantiodivergent non-linear effectKagan's0.60section

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