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Flory–Huggins solution theory

Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing. The result is an equation for the Gibbs free energy change Δ G m i x {\displaystyle \Delta G_{\rm {mix}}} for mixing a polymer with a…

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Theory

Thermodynamic equationGibbs energyTemperaturePressureValue
19 related topics

Derivation

PhasesSoluteMacromolecularChainSymmetry
18 related topics

Limitations

Lower critical solution temperatureTemperatureRadius of gyration
3 related topics

Liquid-liquid phase separation

Osmotic pressure
1 related topics

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Overview

Theory

Derivation

Liquid-liquid phase separation

Polymer blends

Limitations

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Flory–Huggins solution theory

Nodes59
Edges58
Triples1
Avg. degree1.97
Density0.033898
Components1

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Flory–Huggins solution theory

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Flory–Huggins solution theory → lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mi…

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Important terminology

displaystyle polymer solvent mixing energy flory huggins chain entropy theory chi solution lattice molecules interaction polymers parameter small molecular volume

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Flory–Huggins solution theoryis alattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mi…0.90text

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