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In quantum mechanics, the Hellmann–Feynman theorem relates the derivative of the total energy with respect to a parameter to the expectation value of the derivative of the Hamiltonian with respect to that same parameter. According to the theorem, once the spatial distribution of the electrons has been determined by solving the Schrödinger equation, all…
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theorem hellmann feynman displaystyle hamiltonian schrödinger lambda derivative equation parameter psi frac forces variational quantum energy states hat rangle proof
| Subject | Predicate | Object | Confidence | Src |
|---|---|---|---|---|
| Hellmann–Feynman theorem | is a | calculation of intramolecular forces in molecules | 0.90 | text |
| Hellmann–Feynman theorem | related to Alternate proof | The Hellmann | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Feynman | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Rayleigh | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Ritz | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Schrödinger | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | This | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Hellmann | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Hartree | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Fock | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | Hamiltonian | 0.60 | section |
| Hellmann–Feynman theorem | related to Alternate proof | According | 0.60 | section |
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