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Hauser base

Hauser bases, also called magnesium amide bases, are magnesium compounds used in organic chemistry as bases for metalation reactions. These compounds were first described by Charles R. Hauser in 1947. Compared with organolithium reagents, the magnesium compounds have more covalent, and therefore less reactive, metal-ligand bonds. Consequently, they…

Applications, Structures & Preparation and reactions

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Overview

Structures

Preparation and reactions

Turbo-Hauser base

Advanced semantic analysis

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Map overview Semantic statistics

Hauser base

Nodes22
Edges21
Triples25
Avg. degree1.91
Density0.090909
Components1

How this topic connects Entity context

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Hauser base

Top relations

related to Structures · 11
Hauser base → Amido-bridged Hauser, Attached, Et2N, Hauser, HMDS, Mg, Ph3P, R2N, R2NMgX, The, TMP
related to Turbo-Hauser base · 10
Hauser base → Hauser, Improved, In, LiCl, These, They, THF, This, TMPMgCl, Turbo-Hauser
related to Preparation and reactions · 4
Hauser base → Grignard, R2NH, The Hauser, TMP

Important terminology Word statistics

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Important terminology

hauser bases compounds reactions used organolithium reagents metalation base magnesium temperatures tmp solution also less functional group tolerance generally low

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Hauser baserelated to Preparation and reactionsThe Hauser0.60section
Hauser baserelated to Preparation and reactionsGrignard0.60section
Hauser baserelated to Preparation and reactionsR2NH0.60section
Hauser baserelated to Preparation and reactionsTMP0.60section
Hauser baserelated to StructuresHauser0.60section
Hauser baserelated to StructuresR2NMgX0.60section
Hauser baserelated to StructuresThe0.60section
Hauser baserelated to StructuresAttached0.60section
Hauser baserelated to StructuresMg0.60section
Hauser baserelated to StructuresR2N0.60section
Hauser baserelated to StructuresTMP0.60section
Hauser baserelated to StructuresHMDS0.60section

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    Min side: 3
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