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Fluxional molecule

Fluxional (or non-rigid) molecules are molecules that undergo dynamics such that some or all of their nuclei interchange, or tunnel, between symmetrically equivalent positions. Because virtually all molecules are fluxional at some time scale, the term fluxional depends on the method used to assess the dynamics. A molecule is considered to be fluxional if…

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Fluxional molecule

Nodes35
Edges34
Triples39
Avg. degree1.94
Density0.057143
Components1

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Fluxional molecule

Top relations

related to Berry pseudorotation of pentacoordinate compounds · 11
Fluxional molecule → Berry, CO, Fe, Fluorine-19 NMR, In, Iron, Its, NMR, PF5, SF4, The
related to NMR spectroscopy · 10
Fluxional molecule → Beyond, Cope, DNMR, In, Many, NMR, Prior, Temperature, The, Typically
see also · 10
Fluxional molecule → C10H10, Chemical, Dutt, Fluxional, Hapticity, Molecular, Movement, Organic, Pyramidal, Type
related to Dimethylformamide · 7
Fluxional molecule → At, DMF, MHz, Near, NMR, The, This
is a · 1
Fluxional molecule → methanium ion

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Important terminology

fluxional nmr molecule molecules temperature temperatures low spectrum dynamics exchange observed two compounds ir cyclohexane spectra one spectroscopy species pseudorotation

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Fluxional moleculeis amethanium ion0.90text
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsIts0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsNMR0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsFluorine-19 NMR0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsThe0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsBerry0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsIron0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsFe0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsCO0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsPF50.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsIn0.60section
Fluxional moleculerelated to Berry pseudorotation of pentacoordinate compoundsSF40.60section

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