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Dihydrogen complex

Dihydrogen complexes are coordination complexes containing intact H2 as a ligand. They are a subset of sigma complexes. The prototypical complex is W(CO)3(PCy3)2(H2). This class of compounds represent intermediates in metal-catalyzed reactions involving hydrogen. Hundreds of dihydrogen complexes have been reported. Most examples are cationic transition…

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Characterization

Synthesis

History

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Dihydrogen complex

Nodes28
Edges27
Triples27
Avg. degree1.93
Density0.071429
Components1

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Dihydrogen complex

Top relations

related to Characterization · 14
Dihydrogen complex → An, CO, Dihydrogen, For, HD, Hz, In, JHD, Neutrons, NMR, PiPr3, The, X-ray, X-rays
related to history · 12
Dihydrogen complex → CO, Cr, Fe, For, H2, In, Kubas, Mo, PPh3, PR3, RuH4, This

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Important terminology

complexes h2 dihydrogen hydrogen co complex also cases bond ligands described containing characterization see compounds example one reactions reported metals

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Crinstance ofThis result rapidly led to the discovery of a variety of related complexes0.80text
Dihydrogen complexrelated to CharacterizationThe0.60section
Dihydrogen complexrelated to CharacterizationNMR0.60section
Dihydrogen complexrelated to CharacterizationJHD0.60section
Dihydrogen complexrelated to CharacterizationHD0.60section
Dihydrogen complexrelated to CharacterizationFor0.60section
Dihydrogen complexrelated to CharacterizationHz0.60section
Dihydrogen complexrelated to CharacterizationCO0.60section
Dihydrogen complexrelated to CharacterizationPiPr30.60section
Dihydrogen complexrelated to CharacterizationDihydrogen0.60section
Dihydrogen complexrelated to CharacterizationAn0.60section
Dihydrogen complexrelated to CharacterizationNeutrons0.60section

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