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In polymer chemistry, chain termination is any chemical reaction that ceases the formation of reactive intermediates in a chain propagation step in the course of a polymerization, effectively bringing it to a halt. Chain termination contributes to chain length, end-group structure, and other properties such as thermal stability and toughness.
Mechanisms of termination, Termination of radical polymerization & Termination of cationic polymerization
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termination chain polymerization recombination disproportionation monomer anionic radical transfer reaction polymer cationic mechanisms used occur growth two propagating types molecules
| Subject | Predicate | Object | Confidence | Src |
|---|---|---|---|---|
| thermal stability | instance of | and other properties | 0.80 | text |
| toughness.There are multiple types of chain termination depending on the type of polymerization that is being used | instance of | and other properties | 0.80 | text |
| oxygen gas | instance of | termination is commonly induced by the presence of trace impurities | 0.80 | text |
| carbon dioxide | instance of | termination is commonly induced by the presence of trace impurities | 0.80 | text |
| or water molecules | instance of | termination is commonly induced by the presence of trace impurities | 0.80 | text |
| styrene | instance of | monomers | 0.80 | text |
| methacrylate | instance of | monomers | 0.80 | text |
| and vinyl pyridine are often used for anionic polymerization | instance of | monomers | 0.80 | text |
| oxygen gas | instance of | termination can occur through the unintentional reaction between the propagating molecule and a trace impurity | 0.80 | text |
| carbon dioxide | instance of | termination can occur through the unintentional reaction between the propagating molecule and a trace impurity | 0.80 | text |
| and/or water molecules | instance of | termination can occur through the unintentional reaction between the propagating molecule and a trace impurity | 0.80 | text |
| Chain termination | related to Termination of anionic polymerization | Anionic | 0.60 | section |
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