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Carbones

Carbones are a class of molecules containing a carbon atom in the 1D excited state with a formal oxidation state of zero where all four valence electrons exist as unbonded lone pairs. These carbon-based compounds are of the formula CL2 where L is a strongly σ-donating ligand, typically a phosphine (carbodiphosphoranes) or a N-heterocyclic carbene/NHC…

Reactivity, Carbodiphosphoranes & Overview

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Overview

Structure and bonding

Carbodiphosphoranes

Carbodicarbenes

Reactivity

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Carbones

Nodes84
Edges83
Triples29
Avg. degree1.98
Density0.02381
Components1

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Carbones

Top relations

related to Ligands · 8
Carbones → Brønsted-Lowry, Carbodicarbenes, Experimentally, In, Lewis, N-heterocyclic, Several, The
related to Basicity · 7
Carbones → Brønsted-Lowry, Carbodicarbenes, For, However, N-heterocyclic, The, This
related to Reactivity in main group complexes · 3
Carbones → C-H, Carbodicarbenes, The

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Important terminology

carbon carbodiphosphoranes also atom carbodicarbenes two lone strong carbene pairs structure synthesis form n-heterocyclic central complexes main group carbodicarbene first

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
sodium hydride or sodium amide can deprotonate the centre carbon atom to form the desired carbodiphosphoraneinstance ofdiphosphine salt with a strong base0.80text
tungsteninstance ofincluding with metals0.80text
nickelinstance ofincluding with metals0.80text
copperinstance ofincluding with metals0.80text
silverinstance ofincluding with metals0.80text
and goldinstance ofincluding with metals0.80text
rhodiuminstance ofcompound with two lone pairs on the central carbon atom donating to the gold atoms.Carbodicarbenes have also been shown to form complexes with different transition metals0.80text
goldinstance ofcompound with two lone pairs on the central carbon atom donating to the gold atoms.Carbodicarbenes have also been shown to form complexes with different transition metals0.80text
borenium ionsinstance ofCarbodicarbenes have been employed in the successful synthesis of novel boron-containing compounds0.80text
which can exhibit useful optical propertiesinstance ofCarbodicarbenes have been employed in the successful synthesis of novel boron-containing compounds0.80text
as well as a dicationic tricoordinate hydridoboron compoundinstance ofCarbodicarbenes have been employed in the successful synthesis of novel boron-containing compounds0.80text
Carbonesrelated to BasicityThe0.60section

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