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Β-Hydride elimination

β-Hydride elimination is a reaction in which a metal-alkyl centre is converted into the corresponding metal-hydride-alkene. β-Hydride elimination can also occur for many alkoxide complexes as well. The main requirements are that the alkyl group possess a C-H bond β to the metal and that the metal be coordinatively unsaturated. Thus, metal-butyl complexes…

Role of β-hydride elimination, Avoiding β-hydride elimination & Mechanism

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Role of β-hydride elimination

Shell higher olefin processOlefinsZiegler–Natta polymerizationChain walkingNickel
16 related topics

Avoiding β-hydride elimination

NeopentylBredt's rule
2 related topics

Mechanism

Agostic complex
1 related topics

Overview

AlkylHydrideAlkeneButylMethyl
8 related topics

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Overview

Role of β-hydride elimination

Mechanism

Avoiding β-hydride elimination

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Β-Hydride elimination

Nodes32
Edges31
Triples32
Avg. degree1.94
Density0.0625
Components1

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Β-Hydride elimination

Top relations

related to Mechanism · 9
Β-Hydride elimination → Alignment, C-H, Dissociation, Hydride, Hydride Transfer/Alkene Formation, In, M-H, Starting, The
related to Avoiding β-hydride elimination · 6
Β-Hydride elimination → Bredt's, Common, Hydride, Several, The, This
related to Non-dissociative · 5
Β-Hydride elimination → Especially, II, L-type, Pt, This
related to Role of β-hydride elimination · 5
Β-Hydride elimination → Hydride, Natta, The, The Shell, Ziegler
related to Structure-reactivity relationships · 4
Β-Hydride elimination → More, Relative, The, This
related to Further reading · 2
Β-Hydride elimination → Dissociation-induced, Hydride
is a · 1
Β-Hydride elimination → reaction in which a metal-alkyl centre is converted into the corresponding metal-hydride-alkene. β-Hydride elimination can also occur for many alkoxide complexes as well

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Important terminology

β-hydride elimination metal complexes alkyl reaction alkoxide complex ligand bond ligands occur site step metal-alkyl c-h unsaturated higher many group

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
Β-Hydride eliminationis areaction in which a metal-alkyl centre is converted into the corresponding metal-hydride-alkene. β-Hydride elimination can also occur for many alkoxide complexes as well0.90text
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationSeveral0.60section
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationThe0.60section
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationCommon0.60section
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationHydride0.60section
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationThis0.60section
Β-Hydride eliminationrelated to Avoiding β-hydride eliminationBredt's0.60section
Β-Hydride eliminationrelated to Further readingDissociation-induced0.60section
Β-Hydride eliminationrelated to Further readingHydride0.60section
Β-Hydride eliminationrelated to MechanismHydride0.60section
Β-Hydride eliminationrelated to MechanismStarting0.60section
Β-Hydride eliminationrelated to MechanismDissociation0.60section

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