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Autoacceleration

In polymer chemistry, autoacceleration (gel effect) is a dangerous reaction behavior that can occur in free-radical polymerization systems. It is due to the localized increases in viscosity of the polymerizing system that slow termination reactions. The removal of reaction obstacles therefore causes a rapid increase in the overall rate of reaction…

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Autoacceleration

Nodes27
Edges26
Triples28
Avg. degree1.93
Density0.074074
Components1

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Autoacceleration

Top relations

has cause · 10
Autoacceleration → Before, Harborth, However, Norrish, Schultz, Smith, The Brownian, They, This, Trommsdorff
related to Bibliography · 9
Autoacceleration → December, Dvornic, Free Radical Polymerization, Jacovic, Milhailo, Petar, Rate, The Viscosity Effect, Wiley InterScience
related to background · 4
Autoacceleration → The, This, To, Without
related to Results · 4
Autoacceleration → Assuming, Therefore, This, With

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Important terminology

polymerization termination reaction rate viscosity free-radical polymer increases effect norrish molecules systems therefore overall also monomer causes polymers molecular mass

Entity relationships Subject–Predicate–Object triples

SubjectPredicateObjectConfidenceSrc
polystyreneinstance ofsuspension polymerization techniques are employed to make polymers0.80text
Autoaccelerationhas causeNorrish0.60section
Autoaccelerationhas causeSmith0.60section
Autoaccelerationhas causeTrommsdorff0.60section
Autoaccelerationhas causeSchultz0.60section
Autoaccelerationhas causeHarborth0.60section
Autoaccelerationhas causeThey0.60section
Autoaccelerationhas causeThis0.60section
Autoaccelerationhas causeBefore0.60section
Autoaccelerationhas causeHowever0.60section
Autoaccelerationhas causeThe Brownian0.60section
Autoaccelerationrelated to backgroundThe0.60section

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